Mercaptanized dicyclopentadiene compositions and use thereof as a mining chemical collector

ABSTRACT

The present invention discloses polythiol compositions containing monothiotricyclodecenes, dithiotricyclodecanes, and intermolecular sulfide compounds, as well as mining chemical collector compositions containing such polythiol compositions. Flotation processes for recovering metals, such as copper and molybdenum, from ores using the mining chemical collector compositions also are disclosed.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a divisional application of U.S. patent application Ser. No. 15/090,643, filed on Apr. 5, 2016, now U.S. Pat. No. 9,539,587, the disclosure of which is incorporated herein by reference in its entirety.

BACKGROUND OF THE INVENTION

The present invention relates generally to polythiol compositions containing monothiotricyclodecenes, dithiotricyclodecanes, and intermolecular sulfide compounds, and to methods for producing such polythiol compositions. These polythiol compositions can be used in mining chemical collector compositions, and the collector compositions can be used in flotation processes for recovering metals from ores.

SUMMARY OF THE INVENTION

This summary is provided to introduce a selection of concepts in a simplified form that are further described below in the detailed description. This summary is not intended to identify required or essential features of the claimed subject matter. Nor is this summary intended to be used to limit the scope of the claimed subject matter.

Various mining chemical collector compositions and polythiol compositions comprising sulfur-containing compounds are disclosed herein. In one embodiment, a collector composition of this invention can comprise a polythiol composition and water, while in another embodiment, a collector composition can comprise a polythiol composition and a pH control agent, and in yet another embodiment, a collector composition can comprise a polythiol composition and a frothing agent. Accordingly, a particular collector composition of this invention can comprise a polythiol composition, a frothing agent, a pH control agent, and water.

In these and other embodiments, suitable polythiol compositions comprising sulfur-containing compounds are disclosed, and the sulfur-containing compounds can comprise (i) less than 10 wt. % monothiotricyclodecene compounds, (ii) at least 40 wt. % dithiotricyclodecane compounds, and (iii) from 5 to 40 wt. % of a heavy fraction comprising intermolecular sulfide compounds having at least one intermolecular sulfide group (—S—), at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optionally at least one (one, two, etc.) thiol sulfur group (—SH). A representative monothiotricyclodecene compound can have the following structure:

A representative dithiotricyclodecane compound can have the following structure:

A representative intermolecular sulfide compound can have the following structure:

Flotation processes for the recovery of a metal (or metals) from an ore also are disclosed herein. These processes can comprise contacting the ore with any of the collector compositions and/or any of the polythiol compositions disclosed herein. The metal can comprise any suitable transition metal, such as copper, molybdenum, and the like, as well as combinations of two or more metals.

Both the foregoing summary and the following detailed description provide examples and are explanatory only. Accordingly, the foregoing summary and the following detailed description should not be considered to be restrictive. Further, features or variations can be provided in addition to those set forth herein. For example, certain embodiments can be directed to various feature combinations and sub-combinations described in the detailed description.

DEFINITIONS

To define more clearly the terms used herein, the following definitions are provided. Unless otherwise indicated, the following definitions are applicable to this disclosure. If a term is used in this disclosure but is not specifically defined herein, the definition from the IUPAC Compendium of Chemical Terminology, 2^(nd) Ed (1997) can be applied, as long as that definition does not conflict with any other disclosure or definition applied herein, or render indefinite or non-enabled any claim to which that definition is applied. To the extent that any definition or usage provided by any document incorporated herein by reference conflicts with the definition or usage provided herein, the definition or usage provided herein controls.

Herein, features of the subject matter can be described such that, within particular aspects and/or embodiments, a combination of different features can be envisioned. For each and every aspect, and/or embodiment, and/or feature disclosed herein, all combinations that do not detrimentally affect the designs, compositions, processes, and/or methods described herein are contemplated with or without explicit description of the particular combination. Additionally, unless explicitly recited otherwise, any aspect, and/or embodiment, and/or feature disclosed herein can be combined to describe inventive features consistent with the present disclosure.

While compositions and methods are described herein in terms of “comprising” various components or steps, the compositions and methods can also “consist essentially of” or “consist of” the various components or steps, unless stated otherwise. For example, a collector composition consistent with embodiments of the present invention can comprise; alternatively, can consist essentially of or alternatively, can consist of; a polythiol composition, a pH control agent, a frothing agent, and water.

The terms “a,” “an,” and “the” are intended to include plural alternatives, e.g., at least one. For instance, the disclosure of “a solvent,” “a transition metal,” etc., is meant to encompass one, or mixtures or combinations of more than one, solvent, transition metal, etc., unless otherwise specified.

Generally, groups of elements are indicated using the numbering scheme indicated in the version of the periodic table of elements published in Chemical and Engineering News, 63(5), 27, 1985. In some instances, a group of elements can be indicated using a common name assigned to the group; for example, alkali metals for Group 1 elements, alkaline earth metals for Group 2 elements, transition metals for Group 3-12 elements, and halogens or halides for Group 17 elements.

For any particular compound or group disclosed herein, any name or structure presented is intended to encompass all structural isomers, conformational isomers, regioisomers, stereoisomers, and mixtures thereof that can arise from a particular set of substituents, unless otherwise specified. The name or structure also encompasses all enantiomers, diastereomers, and other optical isomers (if there are any), whether in enantiomeric or racemic forms, as well as mixtures of stereoisomers, as would be recognized by a skilled artisan, unless otherwise specified. For example, a general reference to hexene (or hexenes) includes all linear or branched, acyclic or cyclic, hydrocarbon compounds having six carbon atoms and 1 carbon-carbon double bond; pentane includes n-pentane, 2-methyl-butane, and 2,2-dimethylpropane; a general reference to a butyl group includes an n-butyl group, a sec-butyl group, an iso-butyl group, and a t-butyl group; a general reference to cyclododecatriene includes all isomeric forms (e.g., trans,trans,cis-1, 5, 9-cyclododecatriene, and trans,trans,trans-1, 5, 9-cyclododecatriene, among other dodecatrienes); and a general reference to 2,3-pentanediol includes 2R,3R-pentanediol, 2S,3 S-pentanediol, 2R,3 S-pentanediol, and mixtures thereof. Similarly, a reference to an intermolecular sulfide compound, such as the following structure:

includes all structural isomers, conformational isomers, regioisomers, and stereoisomers thereof, as would be recognized by a skilled artisan, and includes the following structures (among others):

In one embodiment, a chemical “group” can be defined or described according to how that group is formally derived from a reference or “parent” compound, for example, by the number of hydrogen atoms removed from the parent compound to generate the group, even if that group is not literally synthesized in such a manner. These groups can be utilized as substituents, can be coordinated or bonded to metal atoms, or can be substituted or unsubstituted. By way of example, an “alkyl group” formally can be derived by removing a hydrogen atom (one or more, as necessary for the particular group) from a carbon atom of an alkane. The disclosure that a substituent, ligand, or other chemical moiety can constitute a particular “group” implies that the well-known rules of chemical structure and bonding are followed when that group is employed as described. When describing a group as being “derived by,” “derived from,” “formed by,” or “formed from,” such terms are used in a formal sense and are not intended to reflect any specific synthetic methods or procedures, unless specified otherwise or the context requires otherwise.

As used herein, “thiol sulfur” means sulfur from a —SH group (thiol group), while “sulfide sulfur” means sulfur from a —S— group (sulfide group). Sulfide sulfur groups encompass both intermolecular sulfide groups and intramolecular sulfide groups. The term “intermolecular sulfide” as used herein refers to sulfide bonds formed by a reaction between two molecules. The term “intramolecular sulfide” refers to sulfide bonds formed by a reaction within a single molecule.

As used herein, a “polythiol composition” refers to a composition comprising polythiol molecules. Polythiol molecules refer to molecules having two or more thiol groups per molecule (e.g., 2, 3, etc., thiol groups). For illustrative purposes, in addition to polythiol molecules having 2 SH groups, a polythiol composition also can contain compounds having only 1 thiol group, compounds having only one sulfur atom present as sulfide sulfur, etc. Furthermore, such polythiol compositions can contain other compounds and components, non-limiting examples of which can include solvents and other materials, as well as residual dicyclopentadiene from which the polythiol composition may be derived.

In some instances, the polythiol composition is described, while in others, the sulfur-containing compounds (i.e., having at least 1 sulfur atom present as thiol sulfur or sulfide sulfur) of the polythiol composition are described. Consequently, within this disclosure, properties associated with polythiol compositions can include contributions from the dicyclopentadiene from which the compositions can be formed, as well as other reactants and by-products. In some circumstances, it can be beneficial to refer only to the sulfur-containing compounds, as if the dicyclopentadiene, other reactants, by-products, and/or solvent are not present in the composition. Accordingly, within this disclosure, the term “sulfur-containing compounds,” used in conjunction with the polythiol composition, refers to organic compounds within the composition that contain at least one sulfur atom present in a thiol sulfur group or sulfide sulfur group, and excludes any non-sulfur-containing compound (e.g., dicyclopentadiene reactant and/or solvent, among others), and excludes any sulfur-containing reactant (e.g., H₂S). In sum, a polythiol composition can include all materials in a composition comprising polythiol molecules, while the sulfur-containing compounds refer only to the compounds within the polythiol composition having at least one sulfur atom present in a —SH or a —S— group.

The terms “contact product,” “contacting,” and the like, are used herein to describe compositions and methods wherein the components are contacted together in any order, in any manner, and for any length of time, unless otherwise specified. For example, the components can be contacted by blending or mixing. Further, unless otherwise specified, the contacting of any component can occur in the presence or absence of any other component of the compositions and methods described herein. Combining additional materials or components can be done by any suitable method. Further, the term “contact product” includes mixtures, blends, solutions, slurries, reaction products, and the like, or combinations thereof. Although “contact product” can, and often does, include reaction products, it is not required for the respective components to react with one another. Similarly, the term “contacting” is used herein to refer to materials which can be blended, mixed, slurried, dissolved, reacted, treated, or otherwise contacted in some other manner. Therefore, the term “contacting” encompasses the “reacting” of two or more components, and it also encompasses the “mixing” or “blending” of two or more components that do not react with one another.

Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the invention, the typical methods and materials are herein described.

All publications and patents mentioned herein are incorporated herein by reference for the purpose of describing and disclosing, for example, the constructs and methodologies that are described in the publications, which might be used in connection with the presently described invention.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides mining chemical collector compositions containing polythiol compositions derived from dicyclopentadiene. While not wishing to be bound by theory, a potential benefit of these collector compositions, which comprise sulfur-containing compounds, is less objectionable odor, as compared to other collector compositions that do not comprise the polythiol heavy fraction, sulfide group (—S— group) functionality, and other compositional attributes disclosed herein. Moreover, in contrast to the prevailing knowledge in the mining chemical collector arts, in which it is believed that good collectors have only one functional group (e.g., like a mercaptan or thiol group) connected to a long-chain hydrocarbon (e.g., a C₁₂ hydrocarbon), it was unexpectedly found in this invention that the compositions disclosed herein provide excellent collector performance in spite of containing two or more functional groups (e.g., sulfide groups, mercaptan or thiol groups), as well as short hydrocarbon chains therebetween.

Polythiol Compositions

Polythiol compositions consistent with embodiments of the invention disclosed and described herein can comprise sulfur-containing compounds, and these sulfur-containing compounds can comprise (i) less than 10 wt. % monothiotricyclodecene compounds, (ii) at least 40 wt. % dithiotricyclodecane compounds, and (iii) from 5 to 40 wt. % of a heavy fraction comprising intermolecular sulfide compounds having at least one intermolecular sulfide group (—S—), at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optionally at least one (e.g., one, two, etc.) thiol sulfur group (—SH).

Monothiotricyclodecene compounds can include the following representative structure:

Dithiotricyclodecane compounds can include the following representative structure:

Unless otherwise specified, any name, structure, formula, or compound disclosed herein is meant to include and encompass “isomers thereof,” even without that specific recitation. For instance, the disclosure of “monothiotricyclodecene compounds” is meant to encompass tricyclodecyl-containing compounds such as the compound shown below (as well as isomers thereof), which can be produced by the addition of H₂S to dicyclopentadiene, as would be recognized by those of skill in the art:

The heavy fraction can comprise intermolecular sulfide compounds having at least one intermolecular sulfide group (—S—), at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optionally at least one thiol sulfur group (—SH). Accordingly, the heavy fraction can comprise an intermolecular sulfide compound having no thiol groups, and/or an intermolecular sulfide compound having one thiol sulfur group, and/or an intermolecular sulfide compound having two thiol sulfur groups. For instance, the heavy fraction can comprise intermolecular sulfide compounds having one thiol sulfur group (—SH), one intermolecular sulfide group (—S—), one tricyclodecanyl group, and one tricyclodecenyl group. Additionally or alternatively, the heavy fraction can comprise intermolecular sulfide compounds having two thiol sulfur groups (—SH), one intermolecular sulfide group (—S—), and two tricyclodecanyl groups.

Illustrative and non-limiting examples of these sulfur-containing compounds having one intermolecular sulfide group (—S—) and two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optional thiol sulfur groups (—SH), can include the following compounds:

Moreover, as would be recognized by those of skill in the art, the sulfur-containing compounds of the polythiol composition can comprise other intermolecular sulfide isomers having the same molecular formulas as these intermolecular sulfide compounds, and such isomeric compounds also are encompassed herein.

In these and other embodiments, the polythiol compositions comprising sulfur-containing compounds disclosed herein can further comprise one or more sulfide molecules having two or more intermolecular sulfide groups (—S—), three or more groups independently selected from tricyclodecanyl groups and tricyclodecenyl groups, and optional thiol sulfur groups (—SH). For instance, the heavy fraction can contain sulfur-containing compounds having two intermolecular sulfide groups (—S—) and three groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optional thiol sulfur groups (—SH). Illustrative and non-limiting examples of such compounds can include the following:

Unless otherwise indicated, the compositional aspects of these polythiol compositions (or of the sulfur-containing compounds of the compositions) are disclosed in wt. %. Any disclosure herein of a compositional aspect in wt. % is also meant to encompass the same compositional aspect in area % (area percentage determined using a gas chromatograph with a F.I.D. detector, as described herein), because the disclosed polythiol compositions are often analyzed or evaluated in this manner. While not wishing to be bound by this theory, it is believed that the amount in area % is very similar to the amount in wt. %, but these respective amounts are not identical or exactly interchangeable. As a representative example, a disclosure that the sulfur-containing compounds of the polythiol composition can contain from 60 wt. % to 80 wt. % of dithiotricyclodecane compounds is meant also to disclose that the sulfur-containing compounds of the polythiol composition can contain from 60 area % to 80 area % of dithiotricyclodecane compounds.

The illustrative and non-limiting examples of polythiol compositions comprising sulfur-containing compounds provided hereinabove also can have any of the characteristics or properties provided below, and in any combination.

In an embodiment, the sulfur-containing compounds of the polythiol composition can contain less than or equal to 10 wt. %, less than or equal to 8 wt. %, less than or equal to 5 wt. %, less than or equal to 3 wt. %, less than or equal to 2 wt. %, less than or equal to 1 wt. %, or less than or equal to 0.1 wt. %, of monothiotricyclodecene compounds. Suitable non-limiting ranges for the amount of monothiotricyclodecene compounds, based on the sulfur-containing compounds of the composition, can include the following ranges: from 0 wt. % to 10 wt. %, from 0 wt. % to 5 wt. %, from 0 wt. % to 2 wt. %, from 0.01 wt. % to 8 wt. %, from 0.01 wt. % to 3 wt. %, from 0.01 wt. % to 1 wt. %, from 0.1 wt. % to 10 wt. %, from 0.1 wt. % to 5 wt. %, from 0.1 wt. % to 2 wt. %, or from 0.1 wt. % to 1 wt. %. Other appropriate ranges for the amount of the monothiotricyclodecene compounds are readily apparent from this disclosure.

In an embodiment, the sulfur-containing compounds of the polythiol composition can contain at least 40 wt. %, at least 50 wt. %, at least 60 wt. %, at least 65 wt. %, at least 70 wt. %, at least 75 wt. %, or at least 85 wt. %, of dithiotricyclodecane compounds. Suitable non-limiting ranges for the amount of dithiotricyclodecane compounds, based on the sulfur-containing compounds of the composition, can include the following ranges: from 40 wt. % to 95 wt. %, from 40 wt. % to 90 wt. %, from 40 wt. % to 80 wt. %, from 50 wt. % to 95 wt. %, from 50 wt. to 90 wt. %, from 50 wt. % to 80 wt. %, from 60 wt. % to 90 wt. %, from 60 wt. % to 85 wt. %, or from 60 wt. % to 80 wt. %. Other appropriate ranges for the amount of the dithiotricyclodecane compounds are readily apparent from this disclosure.

In an embodiment, the sulfur-containing compounds of the polythiol composition can contain at least 5 wt. %, at least 8 wt. %, at least 10 wt. %, or at least 15 wt. % of the heavy fraction (i.e., comprising intermolecular sulfide compounds). Suitable non-limiting ranges for the amount of the heavy fraction, based on the sulfur-containing compounds of the composition, can include the following ranges: from 5 wt. % to 40 wt. %, from 5 wt. % to 35 wt. %, from 5 wt. % to 30 wt. %, from 10 wt. % to 40 wt. %, from 10 wt. % to 35 wt. %, from 10 wt. % to 30 wt. %, from 15 wt. % to 40 wt. %, from 15 wt. % to 35 wt. %, or from 15 wt. % to 30 wt. %. Other appropriate ranges for the amount of the heavy fraction containing intermolecular sulfide compounds are readily apparent from this disclosure.

Generally, the polythiol compositions can contain minimal amounts of sulfur-free olefin-containing compounds, such as dicyclopentadiene. In some embodiments, the amount of sulfur-free olefin-containing compounds in the polythiol composition can be less than or equal to 2 wt. %, less than or equal to 1 wt. %, less than or equal to 0.5 wt. %, less than or equal to 0.25 wt. %, less than or equal to 0.1 wt. %, or less than or equal to 0.05 wt. %. Other appropriate ranges for the amount of the sulfur-free olefin-containing compounds are readily apparent from this disclosure.

The polythiol compositions can be further characterized by the amount of sulfide sulfur (sulfur from a —S— group) present in the sulfur-containing compounds of the composition. For instance, sulfur-containing compounds of the composition can have an average of from 0.5 wt. % to 4.5 wt. % sulfide sulfur. These percentages are based on the total sulfur-containing compounds of the composition, regardless of the number of thiol and/or sulfide groups. In certain embodiments, the sulfur-containing compounds of the polythiol composition can have an average sulfide sulfur content in a range from 0.5 to 4.3 wt. %, from 1 to 4.3 wt. %, from 1.2 to 4.3 wt. %, from 0.5 to 4.2 wt. %, from 1 to 4.2 wt. %, from 1 to 4 wt. %, from 1.2 to 4.2 wt. %, or from 1.2 to 3.8 wt. %. Other appropriate ranges for the average sulfide sulfur content are readily apparent from this disclosure.

Moreover, the polythiol compositions can be further characterized by the amount of thiol sulfur (sulfur from a —SH group) present in the sulfur-containing compounds of the composition. For example, sulfur-containing compounds of the composition can have an average of from 18 wt. % to 30 wt. % thiol sulfur. These percentages are based on the total sulfur-containing compounds, regardless of the number of thiol and/or sulfide groups. In particular embodiments, the sulfur-containing compounds of the polythiol composition can have an average thiol sulfur content of the sulfur-containing compounds that includes the following ranges: from 18 to 29 wt. %, from 18 to 28 wt. %, from 19 to 29 wt. %, from 19 to 28 wt. %, from 20 to 30 wt. %, from 20 to 29 wt. %, from 20 to 28 wt. %, from 20 to 26 wt. %, or from 21 to 25 wt. %. Other appropriate ranges for the average thiol sulfur content are readily apparent from this disclosure.

An illustrative and non-limiting example of a polythiol composition consistent with the present invention can contain sulfur-containing compounds comprising from 40 wt. % to 90 wt. % of dithiotricyclodecane compounds, from 10 wt. % to 40 wt. % of the heavy fraction (i.e., comprising intermolecular sulfide compounds), and less than or equal to 5 wt. % of monothiotricyclodecene compounds. Another illustrative and non-limiting example of a polythiol composition consistent with the present invention can contain sulfur-containing compounds comprising from 60 wt. % to 80 wt. % of dithiotricyclodecane compounds, from 15 wt. % to 35 wt. % of the heavy fraction (i.e., comprising intermolecular sulfide compounds), and less than or equal to 2 wt. % of monothiotricyclodecene compounds. As would be readily recognized by those of skill in the art, the total of these components will be less than or equal to 100 wt. %.

Likewise, in area percentages, an illustrative and non-limiting example of a polythiol composition consistent with the present invention can contain sulfur-containing compounds comprising from 40 area % to 90 area % of dithiotricyclodecane compounds, from 10 area % to 40 area % of the heavy fraction (i.e., comprising intermolecular sulfide compounds), and less than or equal to 5 area % of monothiotricyclodecene compounds. Another illustrative and non-limiting example of a polythiol composition consistent with the present invention can contain sulfur-containing compounds comprising from 60 area % to 80 area % of dithiotricyclodecane compounds, from 15 area % to 35 area % of the heavy fraction (i.e., comprising intermolecular sulfide compounds), and less than or equal to 2 area % of monothiotricyclodecene compounds. As would be readily recognized by those of skill in the art, the total of these components will be less than or equal to 100 area %.

While not wishing to be bound by the following theory, it is believed that a potential and unexpected benefit of the polythiol compositions disclosed herein (and the sulfur-containing compounds of the polythiol compositions disclosed herein) is less objectionable or offensive odor, as compared to other polythiol compositions that do not comprise sulfur-containing compounds with a sulfide group (—S— group), and/or that contain higher amounts of materials lighter than dithiotricyclodecane compounds, and/or that contain higher amounts of materials with shorter GC retention times, and/or that contain higher amounts of non-sulfide monothiol materials.

While not being limited thereto, the polythiol compositions disclosed herein can be polythiol compositions derived from dicyclopentadiene. In some embodiments, the polythiol compositions disclosed herein can be produced by any process described herein. For instance, these polythiol compositions can be produced by a process comprising contacting dicyclopentadiene, H₂S, and optionally, a phosphite compound; and forming the polythiol composition. The molar ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene can be in a range, for example, from 2:1 to 500:1, from 2:1 to 50:1, or from 5:1 to 35:1. Additional information on processes for producing such polythiol compositions is provided herein.

Processes for Producing Polythiol Compositions

In accordance with certain embodiments of this invention, a process for producing a polythiol composition can comprise contacting dicyclopentadiene, H₂S, and optionally, a phosphite compound; and forming the polythiol composition. Generally, the features of the process (e.g., the use of the phosphite compound, the hydrogen sulfide to carbon-carbon double bond ratio, the components of and/or features of the polythiol composition, and the conditions under which the polythiol composition is formed, among others) are independently described herein and these features can be combined in any combination to further describe the disclosed process.

In an embodiment, the contacting step (step 1 of the process) can comprise contacting dicyclopentadiene, H₂S, and additional unrecited materials (e.g., a solvent). In other embodiments, the contacting step can consist essentially of contacting dicyclopentadiene and H₂S; or alternatively, consist of contacting dicyclopentadiene and H₂S. In some embodiments, the contacting step (step 1 of the process) can comprise contacting the dicyclopentadiene, H₂S, the optional phosphite compound, and additional unrecited materials (e.g., a solvent). In other embodiments, the contacting step can consist essentially of contacting dicyclopentadiene, H₂S, and the optional phosphite compound or, alternatively, consist of contacting dicyclopentadiene, H₂S, and the optional phosphite compound. Likewise, additional materials or features can be employed in the forming step (step 2 of the process). For instance, the formation of the polythiol composition can occur in the presence of ultraviolet light, discussed further herein. Moreover, it is contemplated that when the processes for forming polythiol compositions utilize a phosphite compound, the processes can employ more than one phosphite compound. In some embodiments, the contacting step (step 1) and the forming step (step 2) can occur simultaneously; alternatively, the contacting step (step 1) and the forming step (step 2) can occur separately; or alternatively, the contacting step (step 1) and the forming step (step 2) can occur sequentially.

In the processes disclosed herein, the minimum molar ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene can be 2:1, 3:1, 5:1, or 8:1, while the maximum molar ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene can be 500:1, 150:1, 100:1, 50:1, 35:1, or 25:1. Therefore, suitable ranges for the ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene can include, but are not limited to, the following ranges: from 2:1 to 500:1, from 2:1 to 150:1, from 2:1 to 50:1, from 2:1 to 25:1, from 3:1 to 100:1, from 3:1 to 50:1, from 3:1 to 35:1, from 5:1 to 500:1, from 5:1 to 100:1, from 5:1 to 35:1, from 5:1 to 25:1, from 8:1 to 500:1, from 8:1 to 150:1, from 8:1 to 50:1, from 8:1 to 35:1, or from 8:1 to 25:1.

Generally, without being limited to theory, an increase in the ratio of H₂S to carbon-carbon double bonds can be used to increase the average thiol sulfur to sulfide sulfur molar ratio and/or the average thiol sulfur content of the sulfur-containing compounds in the polythiol compositions disclosed herein. In contrast, without being limited to theory, a decrease in the ratio of H₂S to carbon-carbon double bonds generally can be used to increase the mercaptan equivalent weight and/or the average sulfide sulfur content of the sulfur-containing compounds in the polythiol compositions disclosed herein.

When the phosphite compound is used in the processes disclosed herein, the minimum molar ratio of the phosphite compound to carbon-carbon double bonds of the dicyclopentadiene can be 0.0005:1, 0.001:1, 0.005:1, or 0.006:1, while the maximum molar ratio of the phosphite compound to carbon-carbon double bonds of the dicyclopentadiene can be 0.1:1, 0.075:1, or 0.05:1. Therefore, suitable ranges for the molar ratio of the phosphite compound to carbon-carbon double bonds of the dicyclopentadiene can include, but are not limited to, the following: from 0.0005:1 to 0.1:1, from 0.0005:1 to 0.075:1, from 0.0005:1 to 0.05:1, from 0.001:1 to 0.1:1, from 0.001:1 to 0.075:1:1, from 0.001:1 to 0.05:1, from 0.005:1 to 0.1:1, from 0.005:1 to 0.05:1, from 0.006:1 to 0.001:1, from 0.006:1 to 0.05:1, from 0.008:1 to 0.05:1, from 0.008:1 to 0.04:1, from 0.01:1 to 0.1:1, or from 0.01:1 to 0.05:1.

Independently, steps 1 and 2 of the process for forming a polythiol composition can be conducted at a variety of temperatures, pressures, and time periods. For instance, the temperature at which the dicyclopentadiene, H₂S, and the phosphite compound (if used) are initially contacted can be the same as, or different from, the temperature at which the polythiol composition is formed. As an illustrative example, in step 1, the dicyclopentadiene, H₂S, and the phosphite compound (if used) can be contacted initially at temperature T1 and, after this initial combining, the temperature can be increased to a temperature T2 to allow the formation of the polythiol composition. Likewise, the pressure can be different in step 1 than in step 2. Often, the time period in step 1 is referred to as the contact time, while the time period in step 2 is referred to as the reaction time. The contact time and the reaction time can be different; alternatively, the contact time and the reaction time can be the same.

In an embodiment, step 1 of the process for forming a polythiol composition can be conducted at a temperature in a range from −30° C. to 150° C.; alternatively, from −20° C. to 130° C.; alternatively, from −10° C. to 100° C.; alternatively, from −5° C. to 80° C.; alternatively, from 0° C. to 60° C.; or alternatively, from 10° C. to 45° C. In these and other embodiments, after the initial contacting, the temperature can be changed, if desired, to another temperature for the formation of the polythiol composition. Accordingly, step 2 can be conducted at a temperature in a range from −30° C. to 150° C.; alternatively, from −20° C. to 130° C.; alternatively, from −10° C. to 100° C.; alternatively, from −5° C. to 80° C.; alternatively, from 0° C. to 60° C.; or alternatively, from 10° C. to 45° C. These temperature ranges also are meant to encompass circumstances where the forming step can be conducted at a series of different temperatures, instead of at a single fixed temperature, falling within the respective ranges.

In an embodiment, step 1 and/or step 2 of the process of forming a polythiol composition can be conducted at a total reactor pressure in a range from 30 to 1500 psig, such as, for example, from 50 to 1500 psig. In some embodiments, the polythiol formation in step 2 can be conducted at total reactor pressure in a range from 50 to 1500 psig; alternatively, from 50 to 1000 psig; alternatively, from 50 to 750 psig; alternatively, from 50 to 500 psig; or alternatively, from 100 to 500 psig.

The contact time in step 1 of the process is not limited to any particular range. That is, the dicyclopentadiene, H₂S, and the phosphite compound (if used) can be initially contacted rapidly, or over a longer period of time, before commencing the reaction and/or the formation of the polythiol composition in step 2. Hence, step 1 can be conducted, for example, in a time period ranging from as little as about 1-30 seconds to as long as about 1-6 hours. In some embodiments, the contact time can be in a range from 15 minutes to 3 hours, or from 30 minutes to 2 hours. The appropriate reaction time for the formation of the polythiol composition in step 2 can depend upon, for example, the reaction temperature and the molar ratios of the respective components in step 1, among other variables. However, the polythiol composition often can be formed over a time period in step 2 that can be in a range from 1 minute to 8 hours, such as, for example, from 2 minutes to 6 hours, from 5 minutes to 5 hours, from 10 minutes to 4 hours, or from 15 minutes to 3 hours.

In embodiments of this invention, once the dicyclopentadiene, H₂S, and the phosphite compound (if used) are contacted, the polythiol composition can be formed in the presence of electromagnetic radiation. For instance, the polythiol composition can be formed in the presence of ultraviolet light. Additionally or alternatively, the polythiol composition can be formed by light photolysis initiation of a free radical initiator. Additionally or alternatively, the polythiol composition can be formed under conditions suitable for the thermal decomposition of a free radical initiator. Additionally, a photoinitiator can be utilized in conjunction with ultraviolet light or light photolysis initiation of a free radical initiator. Free radicals, therefore, can be generated in situ by a suitable energy source, or can be generated by the thermal decomposition of a free radical initiator, or by a combination of these sources. The polythiol composition can be formed in the presence of free radicals from any one of aforementioned sources, including combinations thereof, but is not limited to free radicals generated only by these means.

In an embodiment, the step 1 contacting of the dicyclopentadiene, H₂S, and the phosphite compound (if used) can be conducted prior to the generation of free radicals and the formation of the polythiol composition in step 2.

When the polythiol composition is formed in the presence of ultraviolet light, ultraviolet light in the range, for example, from 172 to 450 nm, from 172 to 380 nm, or from 172 to 320 nm, can be employed. Ultraviolet light can be supplied from ultraviolet lamps, but other sources of ultraviolet light can be employed, and are to be considered within the scope of the present invention.

The free radical initiator can be any free radical initiator capable of forming free radicals under thermal decomposition or light photolysis. For example, the free radical initiator employed for the formation of the polythiol composition can comprise a —N=N— group, a —O—O— group, or combinations thereof; alternatively, a —N=N— group; or alternatively, a —O—O— group. Free radical initiators, therefore, can include, but are not limited to, peroxy compounds, organic azo compounds, or combinations thereof; alternatively, peroxy compounds; or alternatively, organic azo compounds. Peroxy compounds which can be utilized can include peroxides, hydroperoxides, peroxyesters, diacylperoxides, and percarbonates; alternatively, peroxides; alternatively, hydroperoxides; alternatively, peroxyesters; alternatively, diacylperoxides; or alternatively, percarbonates. In an embodiment, the peroxide can be a dialkyl peroxide. In an embodiment, the hydroperoxide can be an alkyl hydroperoxide. In an embodiment, the peroxy ester can be an alkyl peroxyalkanoate, or alternatively, an alkyl peroxyarenoate. In an embodiment, the diacylperoxide can be a diaroyl peroxide, or alternatively, a diakoyl peroxide. In an embodiment, the percarbonate can be a dihydrocarbyl percarbonate; alternatively, a diarylpercarbonate; or alternatively, a dialkylpercarbonate. Generally, the hydrocarbon and/or alkane group(s) utilized in any peroxy compound can be a C₁ to C₃₀, C₂ to C₁₈, C₂ to C₁₀, or C₂ to C₅ hydrocarbon and/or alkane group(s). Generally, the arene group utilized in any peroxy compound can be a C₆ to C₃₀, C₆ to C₁₈, C₆ to C₁₅, or C₆ to C₁₀ arene group(s). Illustrative non-limiting examples of peroxy compounds which can be utilized can include, but are not limited to, diisobutyryl peroxide, 1-(2-ethylhexanoylperoxy)-1,3-dimethylbutyl peroxypivalate, cumylperoxyneodecanoate, 1, 1,3,3-tetramethylbutyl peroxyneodecanoate, t-butyl peroxyneodecanoate, 1,1,3,3-tetramethylbutyl peroxypivalate, t-butyl peroxyneoheptanoate, t-amyl peroxypivalate, t-butyl peroxypivalate, di(3,5,5-trimethylhexanoyl) peroxide, dilauroyl peroxide, didecanoyl peroxide, 2,5-dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane, 1,1,3,3-tetramethylbutyl peroxy 2-ethylhexanoate, t-amyl peroxy 2-ethylhexanoate, dibenzoyl peroxide, acetyl peroxide t-butyl peroxy 2-ethylhexanoate, t-butyl peroctanoate, t-butyl peroxydiethylacetate, t-butyl peroxyisobutyrate, t-butyl peroxy 3,5,5-trimethylhexanoate, t-butyl peroxyacetate, t-butyl peoxybenzoate, 2,4-dichlorobenzoyl peroxide, t-butylpermaleic acid, di-t-butyl diperphthalate, di(4-t-butylcyclohexyl) peroxydicarbonate, di(2-ethylhexyl) peroxydicarbonate, dibutyl peroxydicarbonate, dicetyl peroxydicarbonate, dimyristyl peroxydicarbonate, t-amylperoxy 2-ethylhexyl carbonate, t-butylperoxy isopropyl carbonate, t-butylperoxy 2-ethyl hexyl carbonate, 1,1-di(t-butylperoxy) 3,5,5-trimethylcyclohexane, 2,2-di(4,4-di(t-butylperoxy)cyclohexyl)propane, 1,1-di(t-butylperoxy)cyclohexane, 2,2-di(t-butylperoxy)butane, di(t-amyl)peroxide, dicumyl peroxide, di(t-butylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, t-butyl cumyl peroxide, 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3, di-t-butyl peroxide, 3,6,9-triethyl-3,6,9-trimethyl-1,4,7-triperoxoane, t-butyl hydroperoxide, methyl benzyl hydroperoxide, octylperbenzoate, methyl ethyl ketone peroxide, acetone peroxide, or combinations thereof.

Non-limiting examples of suitable azo compounds include α,α′-azo diisobutyronitrile (AIBN), azobenzene, azomethane, 2,2′-azodi(2-methylbutyronitrile), 2,2′-azobis(4-methoxy-2,4-dimethyl valeronitrile), dimethyl 2,2′-azobis(2-methylpropionate), 1,1′-azobis(cyclohexane-1-carbonitrile), 1-[(cyano-1-methylethyl)azo] formamide, 2,2′-azobis(N-cyclohexyl-2-methylpropionamide), 2,2′-azobis(2,4-dimethyl valeronitrile), 2,2′-azobis(2-methylbutyronitrile), 2,2′-azobis[N-(2-propenyl)-2-methylpropionamide], 2,2′-azobis(N-butyl-2-methylpropionamide), 2,2′-azobis {2-methyl-N-[1,1-bis(hydroxymethyl)-2-hydroxyethyl] propionamide, 2,2′-azobis[2-methyl-N-(2-hydroxyethyl)propionamide], 2,2′-azobis[2-(2-imidazolin-2-yl)propane], 2,2′-azobis {2-methyl-N-[2-(1-hydroxybutyl)] propionamide}, 2,2′-azobis(2-methylpropionitrile), 4,4′-azobis(4-cyanovaleric acid), 2,2′-azobis(2-methylpropane), 2,2′-azobis(2-methylpropionamidine)dihydrochloride, methylpropionitrile, azodicarboxamide, or combinations thereof.

Generally, the peroxide and azo compound free radical initiators that can be utilized in accordance with the present invention decompose under first order kinetics. Skilled artisans can readily find the first order kinetic parameters which can be utilized to describe the decomposition of a particular free radical catalyst from sources such as chemical suppliers, industry reference publications, and/or open literature publications. Under first order kinetics, the time required for a given fraction (or percentage) of the free radical initiator to decompose, at a specific temperature, into initiating species is independent of the concentration of the free radical. This phenomenon is often stated as a half-life; that is, the time in which one-half of the free radical initiator decomposes under specific conditions (e.g., temperature). According to the first order kinetics, the half-life of a free radical initiator is defined as the time it takes one-half of the initiator to decompose at a particular temperature. Using the available first order kinetic parameters for a particular free radical initiator, the concentration of the free radical initiator present in the reaction mixture can be determined at a particular time during the reaction based upon the knowledge of the amount of free radical initiator added to the reaction, the times at which additional (if any) free radical initiator is added to the reaction, and the temperature profile of the reaction.

When the polythiol composition is formed under conditions utilizing the thermal decomposition of a free radical initiator, the polythiol composition can be formed at a temperature within a temperature range of the 1 hour half-life of the free radical initiator. Alternatively, when the polythiol composition is formed under conditions utilizing the thermal decomposition of a free radical initiator, the polythiol composition can be formed using a free radical initiator having a half-life within a time range at the temperature utilized to form the polythiol composition. For example, step 2 of the process (the formation of the polythiol composition) can be conducted at a temperature within ±25° C. of the 1 hour half-life of the free radical initiator. In other embodiments, the polythiol composition can be formed at a temperature within ±20° C. of the 1 hour half-life of the free radical initiator; alternatively, at a temperature within ±15° C. of the 1 hour half-life of the free radical initiator; alternatively, at a temperature within ±10° C. of the 1 hour half-life of the free radical initiator. In another embodiment, the polythiol composition can be formed using a free radical initiator having a half-life within a range from 0.1 to 10 hours at the temperature the polythiol composition is formed (i.e., in step 2 of the process). Alternatively, the polythiol composition can be formed using a free radical initiator having a half-life ranging from 0.1 to 10 hours, from 0.25 to 4 hours, or from 0.5 to 2 hours, at the temperature the polythiol composition is formed. As above, in some embodiments of this invention, the polythiol composition can be formed at a temperature in a range from −30° C. to 150° C.; alternatively, from −20° C. to 130° C.; alternatively, from −10° C. to 100° C.; alternatively, from −5° C. to 80° C.; alternatively, from 0° C. to 60° C.; or alternatively, from 10° C. to 45° C.

Depending upon the particular free radical initiator, a free radical initiator can produce a different number of free radical reaction-initiating species per mole of free radical initiator; thus, the concentration of the free radical initiator can be stated in terms which describe the number of free radical reaction-initiating species generated per mole of free radical initiator. The term “equivalent” is often used to describe the number of reaction-initiating species produced per mole of free radical initiator. For example, one skilled in the art will readily recognize that di-t-butylperoxide can generate two free radical reaction-initiating species per mole of di-t-butylperoxide, while 2,5-bis(t-butylperoxy)-2,5-dimethylhexane can generate four free radical reaction-initiating species per mole of 2,5-bis(t-butylperoxy)-2,5-dimethylhexane.

In some embodiments, a photoinitiator can be utilized. Commercially available photoinitiators include, by way of example, Irgacure® 184 (1-hydroxy-cyclohexyl-phenyl-ketone), Irgacure® 500 (50% 1-hydroxy-cyclohexyl-phenyl-ketone and 50% benzophenone), Irgacure® 819 (Bis-(2,4,6-trimethylbenzoyl)-phenylphosphineoxide), and Irgacure® 127 (2-hydroxy-1-{4-[4-(2-hydroxy-2-methyl-propionyl)-benzyl]-phenyl}-2-methyl-propan-1-one), all available from Ciba Specialty Chemicals, and Duracure 1173 (2-hydroxy-2-methyl-1-phenyl-1-propanone).

When a free radical initiator is present in step 1 and/or in step 2 of the process, the weight percentage of the free radical initiator, based on the weight of the dicyclopentadiene, can be in a range from 0.05 to 10 wt. %, from 0.1 to 9 wt. %, from 0.2 to 5 wt. %, or from 0.1 to 2 wt. %. When a photoinitiator is present in step 1 and/or in step 2 of the process, the weight percentage of the photoinitiator, based on the weight of the dicyclopentadiene, can be less than or equal to 5 wt. %, less than or equal to 3 wt. %, less than or equal to 2 wt. %, or less than or equal to 1.5 wt. %, and typical non-limiting ranges can include from 0.01 to 5 wt. %, from 0.05 to 5 wt. %, from 0.5 to 3 wt. %, or from 1 to 4 wt. %. Other amounts of the free radical initiator and/or the photoinitiator can be employed depending on the specific process conditions used to form the polythiol composition (e.g., temperature, pressure, time) and the respective ratios of H₂S to dicyclopentadiene and of phosphite compound to dicyclopentadiene, amongst other factors. It is contemplated that more than one free radical initiator, more than one photoinitiator, or combinations of free radical initiator(s) and photoinitiator(s), can be employed.

In an embodiment, the polythiol composition can be formed in the absence of a solvent. However, in other embodiments, the polythiol can be formed in the presence of a solvent. Typically, when used, the solvent can be present in an amount up to 1,000 wt. %, based on the weight of the dicyclopentadiene. Alternatively, the formation of the polythiol can be performed in the presence of a solvent in an amount up to 750 wt. %, up to 500 wt. %, up to 250 wt. %, up to 200 wt. %, up to 150 wt. %, or up to 100 wt. %. When a solvent is utilized, the minimum amount of solvent utilized can be at least 5 wt. %, at least 10 wt. %, at least 25 wt. %, at least 50 wt. %, or at least 75 wt. %, based on the weight of the dicyclopentadiene. Generally, the amount of solvent which can be utilized can range from any minimum amount of solvent disclosed herein to any maximum amount of solvent disclosed herein. In some non-limiting embodiments, the formation of the polythiol can be performed in the presence of a solvent in an amount of from 5 wt. % to 1,000 wt. %, from 10 wt. % to 750 wt. %, from 25 wt. % to 500 wt. %, from 50 wt. % to 250 wt. %, from 50 wt. % to 150 wt. %, or from 75 wt. % to 125 wt. %, based on the weight of the dicyclopentadiene. The solvent can be contacted with the dicyclopentadiene, H₂S, and the phosphite compound (if used) in step 1 of the process, and remain present during the formation of the polythiol composition. Alternatively, the solvent can be added after the initial contacting in step 1. Solvents which can be utilized as the solvent are described herein, and these solvents can be utilized without limitation in the processes described herein.

In the processes for producing a polythiol composition disclosed herein, it is contemplated that at least 60% of the carbon-carbon double bonds of the dicyclopentadiene can react to form a sulfur-containing group in the polythiol composition. Often, at least 65% of the carbon-carbon double bonds of the dicyclopentadiene can react to form a sulfur-containing group; alternatively, at least 70%; alternatively; at least 75%; alternatively, at least 80%; alternatively, at least 85%; alternatively, at least 90%; alternatively, at least 95%; alternatively, at least 98%; or alternatively, at least 99%.

Once formed, the polythiol composition, or specific fractions of the polythiol composition, can be purified and/or isolated and/or separated using suitable techniques which include, but are not limited to, evaporation, distillation, crystallization, extraction, washing, decanting, filtering, drying, including combinations of more than one of these techniques. In one embodiment, the process for producing a polythiol composition can further comprise a step of separating or removing at least a portion of the H₂S, of the phosphite compound (if used), of the dicyclopentadiene, of non-sulfide monothiol compounds, or any combination thereof, from the polythiol composition. For instance, these materials can be separated or removed by distillation, by short path distillation, by wiped film evaporation, or by a combination of these techniques.

Consistent with embodiments of this invention, these processes for producing polythiol compositions can be used to produce any of the polythiol compositions disclosed herein.

Phosphite Compounds

Generally, the phosphite compound employed in certain processes for forming a polythiol composition disclosed herein can comprise, consist essentially of, or consist of, a compound having the formula: P(OR¹)₃.

In this formula, each R¹ independently can be a C₁-C₁₈ hydrocarbyl group; alternatively, a C₁-C₁₀ hydrocarbyl group; alternatively, a C₁-C₅ hydrocarbyl group; alternatively, a C₁-C₁₈ alkyl group; alternatively, a C₁-C₁₀ alkyl group; alternatively, a C₁-C₅ alkyl group; alternatively, a C₆-C₁₈ aryl group; or alternatively, a C₆-C₁₀ aryl group. Accordingly, each R¹ independently can be a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, or a decyl group; alternatively, R¹ can be a methyl group, an ethyl group, a propyl group, a butyl group, or a pentyl group; alternatively, R¹ can be a methyl group; alternatively, R¹ can be an ethyl group; alternatively, R¹ can be a propyl group; alternatively, R¹ can be a butyl group; alternatively, R¹ can be a pentyl group; alternatively, R¹ can be a hexyl group; alternatively, R¹ can be a heptyl group; alternatively, R¹ can be an octyl group; alternatively, R¹ can be a nonyl group; or alternatively, R¹ can be a decyl group. In some embodiments, each R¹ independently can be a phenyl group, a tolyl group, a xylyl group, or a naphthyl group; alternatively, a phenyl group, a tolyl group, or a xylyl group; alternatively, a phenyl group; alternatively, a tolyl group; alternatively, a xylyl group; or alternatively, a naphthyl group.

In accordance with an embodiment of this invention, the phosphite compound can comprise, consist essentially of, or consist of, a trialkylphosphite, or alternatively, a triarylphosphite. In accordance with another embodiment of this invention, the phosphite compound can comprise, consist essentially of, or consist of, trimethylphosphite, triethylphosphite, tributylphosphite, or combinations thereof. Yet, in accordance with another embodiment of this invention, the phosphite compound can comprise trimethylphosphite; alternatively, triethylphosphite; or alternatively, tributylphosphite. In another embodiment, the phosphite compound can comprise, consist essentially of, or consist of, triphenylphosphite.

Solvents

As described herein, the polythiol composition can be formed in the presence of a solvent. The solvent can comprise, consist essentially of, or consist of, a hydrocarbon, an aromatic hydrocarbon, a ketone, an alcohol, an ether, or combinations thereof. Hence, mixtures and/or combinations of solvents can be utilized in the processes of forming polythiol compositions disclosed herein.

In an embodiment, the solvent employed in forming the polythiol composition can comprise, consist essentially of, or consist of, a hydrocarbon solvent. Suitable hydrocarbon solvents can include, for example, aliphatic hydrocarbons, petroleum distillates, or combinations thereof. Aliphatic hydrocarbons which can be useful as the solvent include C₃ to C₂₀ aliphatic hydrocarbons; alternatively, C₄ to C₁₅ aliphatic hydrocarbons; or alternatively, C₅ to C₁₀ aliphatic hydrocarbons. The aliphatic hydrocarbons can be cyclic or acyclic, and/or can be linear or branched, unless otherwise specified.

Non-limiting examples of suitable acyclic aliphatic hydrocarbon solvents that can be utilized singly or in any combination include pentane (n-pentane or a mixture of linear and branched C₅ acyclic aliphatic hydrocarbons), hexane (n-hexane or a mixture of linear and branched C₆ acyclic aliphatic hydrocarbons), heptane (n-heptane or a mixture of linear and branched C₇ acyclic aliphatic hydrocarbons), octane (n-octane or a mixture of linear and branched C₈ acyclic aliphatic hydrocarbons), decane (n-decane or a mixture of linear and branched C₁₀ acyclic aliphatic hydrocarbons), and combinations thereof; alternatively, pentane (n-pentane or a mixture of linear and branched C₅ acyclic aliphatic hydrocarbons), hexane (n-hexane or a mixture of linear and branched C₆ acyclic aliphatic hydrocarbons), heptane (n-heptane or a mixture of linear and branched C₇ acyclic aliphatic hydrocarbons), octane (n-octane or a mixture of linear and branched C₈ acyclic aliphatic hydrocarbons), and combinations thereof; alternatively, hexane (n-hexane or a mixture of linear and branched C₆ acyclic aliphatic hydrocarbons), heptane (n-heptane or a mixture of linear and branched C₇ acyclic aliphatic hydrocarbons), octane (n-octane or a mixture of linear and branched C₈ acyclic aliphatic hydrocarbons), and combinations thereof; alternatively, pentane (n-pentane or a mixture of linear and branched C₅ acyclic aliphatic hydrocarbons); alternatively, hexane (n-hexane or a mixture of linear and branched C₆ acyclic aliphatic hydrocarbons); alternatively, heptane (n-heptane or a mixture of linear and branched C₇ acyclic aliphatic hydrocarbons); or alternatively, octane (n-octane or a mixture of linear and branched C₈ acyclic aliphatic hydrocarbons).

In an embodiment, the solvent employed in forming the polythiol composition can comprise, consist essentially of, or consist of, an aromatic hydrocarbon solvent. Aromatic hydrocarbons can include C₆ to C₃₀ aromatic hydrocarbons; alternatively, C₆ to C₂₀ aromatic hydrocarbons; or alternatively, C₆ to C₁₀ aromatic hydrocarbons. Non-limiting examples of suitable aromatic hydrocarbons that can be utilized singly or in any combination include benzene, toluene, xylene (including ortho-xylene, meta-xylene, para-xylene, or mixtures thereof), and ethylbenzene, or combinations thereof; alternatively, benzene; alternatively, toluene; alternatively, xylene (including ortho-xylene, meta-xylene, para-xylene or mixtures thereof); or alternatively, ethylbenzene.

In an embodiment, the solvent employed in forming the polythiol composition can comprise, consist essentially of, or consist of, a ketone solvent, an alcohol solvent, an ether solvent, or combinations thereof; alternatively, a ketone solvent; alternatively, an alcohol solvent; or alternatively, an ether solvent. Suitable ketones, alcohols, or ethers include C₂ to C₂₀ ketones, alcohols, or ethers; alternatively, C₂ to C₁₀ ketones, alcohols, or ethers; or alternatively, C₂ to C₅ ketones, alcohols, or ethers. Non-limiting examples of suitable ketone solvents can include acetone, ethyl methyl ketone, and combinations thereof. Non-limiting examples of suitable alcohol solvents can include methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, pentanol, hexanol, heptanol, octanol, benzyl alcohol, phenol, cyclohexanol, or combinations thereof. Suitable ether solvents can be cyclic or acyclic, non-limiting examples of which can include dimethyl ether, diethyl ether, methyl ethyl ether, monoethers or diethers of glycols (e.g., dimethyl glycol ether), furans, substituted furans, dihydrofuran, substituted dihydrofurans, tetrahydrofuran (THF), substituted tetrahydrofurans, tetrahydropyrans, substituted tetrahydropyrans, 1,3-dioxanes, substituted 1,3-dioxanes, 1,4-dioxanes, substituted 1,4-dioxanes, or mixtures thereof. In an embodiment, each substituent of a substituted furan, substituted dihydrofuran, substituted tetrahydrofuran, substituted tetrahydropyran, substituted 1,3-dioxane, or substituted 1,4-dioxane, can be a C₁ to C₅ alkyl group.

Mining Chemical Collectors

Embodiments of this invention also are directed to collector compositions (such as mining chemical collector compositions) that comprise any of the polythiol compositions disclosed herein. Unexpectedly, it was found that the polythiol compositions disclosed herein are very effective at removing certain desirable minerals from mining ores.

In one embodiment, a collector composition of this invention can comprise water and any of the polythiol compositions disclosed herein. Often, the amount of water in the collector composition can be greater than 75 wt. %, greater than 95 wt. %, or greater than 99 wt. %, and typical non-limiting ranges include from 75 to 99.99 wt. %, from 95 to 99.99 wt. %, or from 99 to 99.99 wt. % water, based on the total weight of the collector composition.

In another embodiment, the collector composition of this invention can comprise any of the polythiol compositions disclosed herein and a suitable pH control agent. Illustrative pH control agents can include, but are not limited to, lime, carbonate compounds, and the like, as well as combinations thereof. In yet another embodiment, the collector composition can comprise any of the polythiol compositions disclosed herein and a suitable frothing agent.

Illustrative frothing agents can include, but are not limited to, pine oil; alcohols such as methyl isobutyl carbinol (MIBC); and polyether alcohols such as NALFLOTE® 9837 and Cytec OREPREP® X-133. Combinations of more than one frothing agent can be used. In still another embodiment, the collector composition can comprise any of the polythiol compositions disclosed herein, a frothing agent, a pH control agent, and water. The amount of the polythiol composition present in the collector composition (excluding the weight of water) typically can be less than 0.1 wt. %, less than 0.01 wt. %, less than 0.001 wt. %, or less than 0.0001 wt. %.

Collector compositions consistent with this invention can comprise a polythiol composition and can contain other components—such as frothing agents, pH control agents, water, and others—and these compositions can be contacted with an ore, as described further hereinbelow. Any suitable order of contacting any components of the collector composition with the ore can be used; and such collector compositions, whether solutions, slurries, blends, immiscible mixtures (e.g., in some instances, the polythiol composition is not soluble/miscible in water), and so forth, are encompassed herein. For instance, a ground ore can be contacted with, in any order, a polythiol composition, a frothing agent, a pH control agent, and a first amount of water (which can be relatively small), resulting in a slurry of the ore and a collector composition comprising the polythiol composition, the frothing agent, the pH control agent, and water. In some embodiments, a second amount of water (which can be relatively large) can be added to this slurry prior to the flotation process, resulting in a slurry of the ore in a collector composition comprising lower concentrations of the polythiol composition, the frothing agent, and the pH control agent. Other suitable methods and orders of forming the collector compositions, whether in the presence of the ore or not, would be readily recognized by those of skill in the art, and such are encompassed herein.

Moreover, the polythiol compositions disclosed herein can be used alone or in combination with other suitable (second) collector agents. Thus, any of the collector compositions can further comprise a second collector agent, non-limiting examples of which can include a xanthate, a xanthic ester, a thionocarbonate, a dialkyl dithiophosphate, and the like, as well as combinations thereof.

Also provided herein are flotation processes for the recovery of metals from ores. The metal can be recovered in any form, for instance, a metal-containing compound (e.g., copper sulfides, molybdenum sulfides), a metal ion, or elemental metal, as well as combinations thereof. One such flotation process for the recovery of a metal from an ore can comprise contacting the ore with any of the collector compositions disclosed herein (or any of the polythiol compositions disclosed herein). Equipment and techniques for the flotation recovery of various metals from mining ores are well known to those of skill in the art, and are illustrated representatively herein in the examples that follow.

Generally, the metal recovered from the ore comprises a transition metal, one or more Group 3-12 metals. In some embodiments, the metal can comprise a Group 3-11 transition metal, or a Group 5-12 transition metal, while in other embodiments, the metal can comprise gold, silver, platinum, copper, nickel, iron, lead, zinc, molybdenum, cobalt, or chromium, as well as combinations thereof. In particular embodiments of this invention, the metal can comprise copper and molybdenum; alternatively, copper; or alternatively, molybdenum. In addition, other transition metals, such as iron, can be recovered along with copper and/or molybdenum.

The flotation processes and mining chemical collector compositions described herein are not limited to any particular ore. However, the effectiveness of such processes and compositions are particularly beneficial when the ore comprises a copper-bearing ore, a molybdenum-bearing ore, or a copper-bearing and molybdenum-bearing ore. Illustrative and non-limiting examples of such ores include chalcopyrite, chalcocite, and the like.

Any suitable amount of the collector composition and/or the polythiol composition can be used in the flotation recovery processes. Often, but not limited thereto, the collector composition (excluding the weight of water in the collector composition) and the ore are contacted at a weight ratio in a range from about 0.001 lb of the collector composition per ton of ore to about 10 lb of the collector composition per ton of ore, or from about 0.01 lb of the collector composition per ton of ore to about 5 lb of the collector composition per ton of ore (excluding the weight of water in the collector composition).

Unexpectedly, the polythiol compositions disclosed herein, and any resultant collector compositions containing the polythiol compositions, have high recovery rates of certain transition metals. For example, the % recovery of copper in the flotation process can be at least about 75 wt. %, at least about 80 wt. %, at least about 85 wt. %, or at least about 90 wt. %, and often as high as 95-98 wt. %. Similarly, the % recovery of molybdenum in the flotation process can be at least about 75 wt. %, at least about 80 wt. %, at least about 85 wt. %, or at least about 90 wt. %, and often as high 97-99 wt. %. Percent (%) recovery is defined as the total amount of metal recovered after the flotation process compared to the total amount of metal present in the ore prior to the flotation process.

Furthermore and surprisingly, in some embodiments, the % recovery of copper, the % recovery of molybdenum, or the % recovery of copper and molybdenum, can be greater than that of a mine standard, under the same flotation conditions. As would be recognized by those of skill in the art, a mine standard is the prevailing collector composition currently being used for a given ore and/or desired transition metal. Mine standards are discussed in greater detail in the examples that follow. In some embodiments, the % recovery of copper, the % recovery of molybdenum, or the % recovery of copper and molybdenum, can be within about 5 wt. %, within about 3 wt. %, within about 2 wt. %, or within about 1 wt. %, of the mine standard, under the same flotation conditions.

Additionally or alternatively, the % recovery of copper, the % recovery of molybdenum, or the % recovery of copper and molybdenum, can be greater than that of a mining collector composition containing TDDM (tertiary dodecyl mercaptan) or NDDM (n-dodecyl mercaptan), under the same flotation conditions. Thus, in some instances, the polythiol compositions disclosed herein are superior to TDDM and/or NDDM. In other embodiments, the % recovery of copper, the % recovery of molybdenum, or the % recovery of copper and molybdenum, can be within about 5 wt. %, within about 3 wt. %, within about 2 wt. %, or within about 1 wt. %, of that achieved with TDDM and/or that achieved with NDDM, under the same flotation conditions.

EXAMPLES

The invention is further illustrated by the following examples, which are not to be construed in any way as imposing limitations to the scope of this invention. Various other aspects, embodiments, modifications, and equivalents thereof which, after reading the description herein, may suggest themselves to one of ordinary skill in the art without departing from the spirit of the present invention or the scope of the appended claims.

Product composition information based upon GC-FID data is presented in area percentages, unless otherwise specified. GC-FID analysis was performed on an Agilent® 7890 gas chromatograph using a 2 m×0.25 mm×1.0 μm film DB-1 capillary column with a flame ionization detector using helium as the carrier gas. A sample of the product composition was dissolved in acetone at a 3:1 acetone to product sample ratio and 0.4 μL of the diluted sample product was injected into a split/splitless PVT inlet. The GC inlet parameters were an inlet temperature of 275° C., an initial inlet pressure of 2.4 psi, a final inlet pressure of 5.2 psi, constant flow conditions of 2 mL/minute of helium, and an inlet split ratio of 50:1. The temperature program for the GC-FID analysis was an initial temperature of 70° C. for 2 minutes, followed by a temperature ramp of 8° C./minute to 200° C., followed by a temperature ramp of 15° C./minute to 300° C. and a temperature hold at 300° C. for 10 minutes. The GC-FID detector was operated at a temperature of 300° C., having a hydrogen gas flow of 25 mL/minute, an air flow of 300 mL/minute, and a makeup helium gas flow of 25 mL/minute. GC-FID analysis data was acquired with Agilent Chemstation®.

Weight percentage of thiol sulfur (wt. % SH) was determined by iodine titration, and weight percentage of total sulfur (wt. % Total S) was determined by x-ray analysis.

Raman spectroscopy was performed with a Kaiser Optical System R_(XN)2 spectrometer and by observing certain wavenumber ranges for olefin conversion, such as at 1572 cm⁻¹ and/or at 1615 cm⁻¹.

Samples were analyzed for molybdenum content by digesting an ore sample over heat in a solution containing potassium chlorate, nitric acid, and hydrochloric acid. After the digested sample was cooled, super floc was added, and the sample was analyzed via atomic absorption using a nitrous oxide-acetylene red flame. Standards ranged from 50-100 ppm by weight molybdenum. A similar procedure with the necessary modifications was used to analyze for copper content and iron content.

Table I summarizes calculated product characteristics for sulfur-containing compounds derived from dicyclopentadiene. In Table I, N is the total number of substituted tricyclodecanyl and tricyclodecenyl moieties, —SH is the number of thiol groups, —S— is the number of sulfide groups, Total S is the total number of sulfur atoms, MW is the molecular weight of the sulfur-containing compound (g/mol), % SH is the wt. % thiol sulfur, % Sulfide is the wt. % sulfide sulfur, % Total S is the wt. % sulfur, and Ratio SH/S is the ratio of thiol sulfur to sulfide sulfur.

Table II summarizes calculated product characteristics for illustrative polythiol compositions derived from dicyclopentadiene. In Table II, the amount of the respective sulfur-containing compounds in the composition is shown in wt. %, % SH is the wt. % thiol sulfur of the composition, % Sulfide is the wt. % sulfide sulfur of the composition, and % Total S is the wt. % sulfur of the composition. Table II illustrates the impact of the relative amounts of the components of the composition on the amount of thiol sulfur and sulfide sulfur in the composition, and particularly the impact of the heavy fraction, which contains intermolecular sulfide compounds.

Examples 1-10 Polythiol Compositions Produced from Dicyclopentadiene

A 1.5-L ultraviolet light reactor was used for Examples 1-2; the working volume was 1.2 L. A 5-L ultraviolet light reactor was used for Examples 3-10; the working volume was 4 L. Each stainless-steel reactor had a quartz lamp well mounted horizontal to an off-set stir shaft. The reactors were equipped with a thermowell, cooling coils, a charge port, a sample port, and a bottom drain valve. Dicyclopentadiene, the phosphite compound (triethylphosphite (TEP)), and the photoinitiator (Irgacure 500) were dissolved in the desired amount of acetone and charged to the reactor through the charge port. The reactor was sealed and pressure checked with nitrogen at 450 psig. The reactor was vented and the desired amount of H₂S was charged to the reactor. The reactor contents were heated and controlled by setting the external circulating bath at the desired temperature of about 25-30° C. for UV-initiated Examples 1-10. The operating pressure ranged from about 300 to 450 psig.

The reaction mixture was allowed to mix for 15 to 30 minutes. After this mixing period, the ultraviolet lamp was turned on, and the olefin conversion to a sulfur-containing group was monitored by observing olefin peaks using Raman spectroscopy. The ultraviolet lamp typically required 3-5 minutes to reach full power. The ultraviolet lamp power was 100 watts.

When the conversion of carbon-carbon double bonds was complete or the desired reaction time was reached, the ultraviolet lamp was turned off. The H₂S was then slowly vented from the reactor. The reaction product was placed in a rotoevaporator at 60° C. and low vacuum to remove additional residual H₂S. The crude polythiol compositions of Examples 1-10 were analyzed using gas chromatography (GC) and data presented in area percentages, unless otherwise specified. GC analysis of the sulfur-containing compounds excluded peaks attributed to phosphorus-containing materials.

Table III summarizes certain process conditions and analytical results for the crude polythiol compositions of Examples 1-10. In Table III, the time (minutes) was the total time in the reactor, and the % conversion (Raman) was the conversion of olefin groups to sulfur-containing groups. For the GC analysis (area %), % TETP was the amount of triethylthiophospate (produced from the TEP), % monothiotricyclodecenes was the amount of monothiotricyclodecene compounds, % dithiotricyclodecanes was the amount of dithiotricyclodecane compounds, and % heavies was the amount of compounds having at least one intermolecular sulfide group (—S—) and at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group (and, for example, 0, 1, or 2 thiol groups).

Examples 1-10 produced polythiol compositions containing approximately 34-48 area % monothiotricyclodecene compounds, 39-49 area % dithiotricyclodecane compounds, and 7-15 area % heavy fraction.

Example 11 Distillation of Polythiol Compositions Produced from Dicyclopentadiene

The crude polythiol compositions produced in Examples 3-10 were combined to form a polythiol composition characterized by approximately 37 area % monothiotricyclodecene compounds, 46 area % dithiotricyclodecane compounds, and 13 area % heavy fraction. This polythiol composition was subjected to laboratory vacuum distillation. The distillation conditions were a pressure of 1-3 torr, a condenser temperature of 15° C., a kettle temperature at reflux in the 119-132° C. range, a head temperature at reflux in the 41-88° C. range, a final kettle temperature in the 163-170° C. range, and a final overhead temperature in the 92-110° C. range.

Example 11 was the resultant distillation (kettle) sample. The distillation process removed a substantial portion of the monothiotricyclodecene compounds, resulting in the polythiol composition of Example 11 containing approximately 0.6 area % monothiotricyclodecene compounds, 68 area % dithiotricyclodecane compounds, and 24-25 area % heavies (while not wishing to be bound by the following theory, it is believed that the balance may include residual solvent and unidentified light compounds). It is also believed that due to the preferential removal of the relatively lighter fractions, the polythiol composition of Example 11 had no offensive odor. While not wishing to be bound by the following theory, it is believed that further conversion to produce sulfide heavies may be occurring in the distillation process, in addition to simply removing the lighter fraction from the crude polythiol compositions.

Examples 12-19 Flotation Recovery of Mining Chemicals

The procedures for the evaluation of different ores and the flotation recovery of various metals are different, but each generally starts with a grind size determination to determine the desired grind time to give a sample with the correct particle size distribution according to the US Standard mesh scale. An appropriate amount of ore from the appropriate mine (900 to 1000 grams, depending on the ore) was provided at the −10 mesh size. This ore was placed in a rod mill with 20 lb of rods with prescribed sizes, and an appropriate amount of water was added to give the desired solids content. The rod mill was turned on for the desired amount of time. This time was based on prior knowledge of that ore sample or an educated guess based on experience of similar ore materials. After grinding for the desired amount of time, the sample was poured and rinsed with a minimum amount of tap water into a container. The water and solids were poured through a 230 mesh wet screen sieve shaker while washing with water to remove any fines. This was done in two batches to facilitate the washing procedure. Failure to remove the fines often can result in the material being glued together in chunks, analogous to concrete. The remaining solids were removed from the screen with washing onto filter paper in a Buchner funnel with vacuum. The solids collected were dried in an oven overnight at 75° C. The dried solids were then screened through a series of screens (25 mesh, 40, 50, 70, 100, 140, 200, 230, and Pan) on a Ro-Tap® shaker in two batches, six minutes each. A total of three or more grind experiments were required to bracket the desired grind time and give a graph of time vs. wt. % dry solids on a certain mesh screen size.

For example, the grind size was 30 wt. %+100 mesh solids (meaning 30% of the particles are 149 microns or larger) for Ore 1, 36 wt. %+100 mesh solids (meaning 36% of the particles are 149 microns or larger) for Ore 3, 20 wt. %+100 mesh solids (meaning 20% of the particles are 149 microns or larger) for Ore 4, and 25 wt. %+70 mesh solids (meaning 25% of the particles are larger than 210 microns) for Ore 2. The +100 includes everything collected on the 100 screen and larger (such as 25, 40, etc.). From the linear plot of this data, the ideal grind time was determined by adding the amount of solids on the screens up to the desired mesh size. From the plot of this data, the desired grind time was determined. This procedure can be done periodically, but is necessary if the ore type or the rod charge changes.

The compositions of each ore evaluated herein are summarized in Table IV. Values are shown in wt. % for copper, iron, molybdenum, sulfur, and total insolubles.

The standard flotation procedure for Ore 1 chalcopyrite is as follows. A 1-kg charge of Ore 1 was added to a rod mill along with 650 mL tap water and approximately 1 g of lime (this amount can be adjusted to obtain the desired alkalinity, see below). The flotation collector reagents were added to the pool of water (not directly on the solids) in the mill using micro syringes: PAX (potassium amyl xanthate), 0.01 lb/ton @ 1% solution (1000 μL), made fresh daily; medium cycle oil (MCO), 0.05 lb/ton, 24.6 μL; MC 37 collector (mixture of TDDM and MCO), 0.05 lb/ton (26.1 μL); and plant frother (80% Nalco NALFLOTE® 9837/20% Cytec OREPREP® X-133), 28 μL. The mill was placed on rubber rollers and ground for the predetermined time. The mill was removed from the rollers and the solids washed into a transparent plastic flotation cell (2.5 L). Only enough water was used to reach the flotation volume (2-liter mark on flotation cell). If too little water was used to wash the material into the flotation cell, additional lime water was added to reach the 2-liter flotation volume. The solids amount was about 32 wt. % for Ore 1. The material was conditioned for two min at 1200 rpm, then floated for five min at 1200 rpm. Air was bubbled into solution at the rate of 8 L/min. Froth was removed from the surface of the cell approximately every 10 sec with a plastic paddle. The froth was collected in a glass pan under the lip of the cell. Liquid was added periodically to keep the solution near the lip of the cell so froth could be easily removed. Care was taken to not have froth flow over the lip without raking with the paddle. The standpipe and back cell corners were washed down as needed with lime water. Depending on the frothiness of the ore, it may be necessary to restrict the air at the beginning of the flotation to prevent froth from overflowing the cell on its own. Generally, the air valve was completely open by the end of the first minute. If not, then the amount of frother was adjusted. If it was difficult to maintain complete surface coverage with froth, a few more microliters of frothing agent were added. To do this, the air and timer were shut off, the froth concentrate added and conditioned for 30 sec before turning back on the air and timer.

The air and stirring were turned off and the apparatus washed to remove solids from the stirrer and shaft into the flotation cell. After allowing the solids to settle for a few minutes, a sample was taken for titration to determine alkalinity. The remaining tails were filtered through an 8 inch stainless steel filter (3 gal) onto shark skin filter paper. The collected solids were dried in an oven at 85° C. overnight to give dry solids that were weighed and labeled as tailings.

The rougher froth concentrate collected in the pan was filtered by washing onto filter paper and dried in an oven at 85° C. overnight. Temperature was kept at/below 85° C. to prevent oxidation and weight changes from occurring. The dried solids were weighed and labeled as concentrate. Both the tailings and concentrate were analyzed for determination of copper, molybdenum, and iron.

The alkalinity titration procedure defined an alkalinity of 1.0 as being equivalent to 0.01 lb of CaO per ton of solution. To prepare lime water of 30 alkalinity, 19 g of CaO were added to 50 L of water, agitated for at least one hour, then solids were settled overnight. The lime water was decanted for use. For titration, to a 50 mL alkaline solution, one drop of phenolphthalein indicator solution was added, and titrated with 0.02N H₂SO₄ solution until the pink color disappeared. Each mL of titrating solution equaled 2.0 alkalinity units.

Assuming a solution is 30 alkalinity, that is, 0.3 lb CaO per ton of solution, then, (0.3 lb CaO/ton solution)*(ton/2000 lb)*(8.345 lb/gal)*(gal/3.785 L)*(453.6 g/lb) converts to 0.15 g CaO/L, or 0.0075 g CaO/50 mL.

If the molecular weight of CaO=56 g/mol, and the molecular weight of H₂SO₄=98 g/mol, and N=(Molarity)*(net positive charge), then 0.02N H₂SO₄=(0.02/2)*(98 g/mol)=(0.98 g/L)*(1 L/1000 mL)=0.00098 g/mL.

-   -   According to the stoichiometry of the reaction:         CaO+H₂SO₄=CaSO₄+H₂O,     -   then 98 g H₂SO₄ neutralizes 56 g CaO.     -   If 0.0075 g CaO are present, then 0.0075×98/56=0.013125 gm H₂SO₄         are required, and 0.013125 g H₂SO₄/0.00098 g/mL=13.393 mL H₂SO₄.

The standard flotation procedure for Ore 2 is as follows. The grind size was determined as described hereinabove for Ore 1. The optimum grind time was 9 min. One kg bag of ore was charged and 650 mL of water was added to the rod mill. The flotation procedure was carried out as described for the Ore 1, except a time of 9 min was used for the new ore and 12 min 18 sec for the old ore. The standard collector system for this ore was added to the grind: 14 μL of Cytec AERO® MX 7021 and 12.5 μL of Cytec AERO® XD 5002—both of which are modified thionocarbamates. The frother added in the flotation cell was Cytec OREPREP® X-133 at 5.6 μL dosage. The pH was adjusted to 11 with lime and the mixer was started at 1200 rpm for 1 min during the conditioning phase. The air was started and the froth was scraped for 6 min into one pan. The air was turned off and the final pH was checked. The concentrate and tailings materials were filtered, dried and weighed as described for the Ore 1 process.

The standard flotation procedure for Ore 3 is as follows. The grind size was determined as described hereinabove for Ore 1. The optimum grind time was 5 min 7 sec. A 900-g charge of ore, 0.6 g of lime, 32.5 μL of diesel, and 600 mL of water were charged into the rod mill. The optimum grind time was utilized and the material transferred to the flotation cell as described above in the Ore 1 procedure. Then, 1091 μL of a 1% solution of sodium ethyl xanthate and 28 μL of the 80/20 frother mentioned in the Ore 1 procedure were charged to the stirring liquid and conditioned for one min. The froth was collected for 3 min into a collection pan. The air was stopped and another 28 μL of frother and 546 μL of 1% sodium ethyl xanthate were added to the slurry. The air was restarted and a 1-min conditioning phase was performed. The froth was then collected for another 2 min into the collection. The concentrate and tailings material were filtered, dried and weighed as described for the Ore 1 process.

The standard flotation procedure for Ore 4 is as follows. The grind size was determined as described hereinabove for Ore 1, except the desired grind for Ore 4 was 20% plus 100 mesh (meaning 20% of the particles are 149 microns or larger). The optimum grind time to achieve these results was 13.75 min. A 1-kg charge of ore was utilized. The amount of lime added to the grind was 1.2 g along with 500 μL of the PAX/dithiophosphate (DTP) 238 solution. The PAX/DTP 238 solution was prepared by mixing 153 mL of distilled water with 0.5 mL DTP 238 and 0.5 gram of PAX. The pH of the slurry was 10.5 after diluting with 650 mL of water and transferring to the flotation cell and diluting with water up to the 2-L mark. The slurry was stirred without air and 2000 μL of PAX/DTP 238 solution were added along with 34 μL of a 50/50 vol. mixture of pine oil/MIBC. The pulp was stirred at 1200 rpm for one min and then the 8 L/min air was turned on. The froth was then raked over the weir for 3 min into a pan. The air was turned off and an additional 34 μL of pine oil/MIBC (frother) and 2000 μL of PAX/DTP were added followed by conditioning for 1 min. The air was then turned back on and the froth collected for an additional 3 min into the pan. The air was then turned off while adding another 34 μL of pine oil/MIBC and 2000 μL of PAX/DTP followed by conditioning for 1 min while stirring. The air was then turned on for another min, followed by collecting the froth for 3 min. The air and stirring were then turned off and the concentrate pan was removed and the pulp mixture vacuum filtered to give the concentrate that was then dried in an oven overnight at 85° C. The tailings mixture was then poured out into a filter with filter paper to obtain a wet tailings mixture. This mixture was dried in an oven overnight at 85° C. The weight of the concentrate and tailings were recorded before analytical analysis.

Table V summarizes Examples 12-19 and the wt. % recoveries of copper, molybdenum, and iron from the four ores tested, using the standard mining chemical collector for each ore and a polythiol composition of this invention at different amounts. Duplicates of each flotation experiment were conducted, and the average was reported. The polythiol composition used was the composite, low odor, polythiol composition of Example 11. The polythiol composition used in the flotation testing (Examples 13, 15, 17, and 19) contained approximately 0.6 area monothiotricyclodecene compounds, 68 area % dithiotricyclodecane compounds, and 24-25 area % heavies.

The standard for Ore 1 (Example 14) was a collector composition (per ton basis) containing 1200 g of lime, 1000 μL of 1% potassium amyl xanthate (PAX), 25 μL of medium cycle oil (MCO), 26 μL of MC 37 (mixture of TDDM and MCO), and 28 μL of plant frother 80% Nalco NALFLOTE® 9837/20% Cytec OREPREP® X-133. Example 15 for Ore 1 used a collector composition containing 1200 g of lime, 15 μL of the polythiol composition, and 28 of plant frother 80% Nalco NALFLOTE® 9837/20% Cytec OREPREP® X-133.

The standard for Ore 3 (Example 12) was a collector composition (per ton basis) containing 600 g of lime, 1637 μL of a 1% sodium ethyl xanthate solution in water, 32.5 μL of diesel, and 56 μL of pine oil/MIBC (frother). Example 13 for Ore 3 used a collector composition containing 600 g of lime, 15 μL of the polythiol composition, and 56 μL of pine oil/MIBC (frother).

The standard for Ore 2 (Example 16) was a collector composition (per ton basis) containing 600 g of lime, 12.5 μL of thionocarbamate Cytec AERO® XD 5002, 14 μL of thionocarbamate MX 7021, and 20 μL of frother Cytec AERO® X-133. Example 17 for Ore 2 used a collector composition containing 600 g of lime, 25 μL of the polythiol composition, and 20 μL of Cytec OREPREP® X-133 (frother).

The standard for the Ore 4 (Example 18) was a collector composition (per ton basis) containing 1100 g of lime, 6500 μL of 1% PAX/DTP 238, and 102 μL of pine oil/MIBC (frother). Example 19 for the Ore 4 used a collector composition containing 1100 g of lime, 15 of the polythiol composition, and 102 μL of pine oil/MIBC (frother).

As shown in Table V, and unexpectedly, the collector compositions used in Examples 13 and 15 (containing polythiol compositions disclosed herein) had % recoveries of copper and molybdenum, independently, of over 85 wt. %. Also, unexpectedly, the collector composition used in Example 19 (containing a polythiol composition disclosed herein) had a % recovery of molybdenum of over 85 wt. %. Moreover, and quite surprisingly, the % recovery of molybdenum in Example 13 was superior to the mine standard of Example 12, the % recovery of molybdenum in Example 15 was superior to the mine standard of Example 14, and the % recovery of molybdenum in Example 19 was far superior to the mine standard of Example 18. Table V demonstrates that the collector compositions used in Examples 13, 15, and 19 were very good copper collectors, but more surprisingly, were excellent molybdenum collectors. The collector composition used in Example 17 was successful in recovering significant percentages of copper and molybdenum, but was not as efficient as the current mine standard for Ore 2.

In addition to the testing results summarized in Table V, experiments similar to Example 13 were performed, but with 9 or 25 μL of the polythiol composition, and the wt. % recoveries for Cu, Mo, and Fe ranged from 92.5-93.6%, 96.0-96.9%, and 38.4-42.3%, respectively. Additional experiments similar to Example 15 also were performed, but with 9 or 25 μL of the polythiol composition, and the wt. % recoveries for Cu, Mo, and Fe ranged from 85.2-88.0%, 93.8-95.2%, and 19.0-23.0%, respectively. Additional experiments similar to Example 17 also were performed, but with 9 or 15 μL of the polythiol composition, and the wt. % recoveries for Cu, Mo, and Fe ranged from 53.8-54.6%, 63.0-63.6%, and 13.7-14.6%, respectively. And lastly, additional experiments similar to Example 19 were performed, but with 9 or 25 μL of the polythiol composition, and the wt. % recoveries for Cu, Mo, and Fe ranged from 70.7-74.5%, 79.7-86.6%, and 16.6-25.3%, respectively.

Examples 20-25 Flotation Recovery of Mining Chemicals

The flotation experiments of Examples 20-25 were performed similarly to Example 15 (containing a polythiol composition). As shown in Table VI, Examples 20-24 substituted TDDM and Example 25 substituted NDDM in place of the polythiol composition used in Example 15. Unexpectedly, the collector composition used in Example 15 (containing a polythiol composition disclosed herein) had a similar % recovery of copper and a superior % recovery of molybdenum, as compared to that of that of mining collector compositions containing either TDDM (tertiary dodecyl mercaptan) or NDDM (n-dodecyl mercaptan), under the same flotation conditions.

TABLE I Calculated product characteristics for polythiol components derived from dicyclopentadiene. Component N —SH —S— Total S MW % SH % Sulfide % Total S Ratio SH/S Monothiotricyclodecene 1 1 0 1 166.3 19.28 0.00 19.28 — Dithiotricyclodecane 1 2 0 2 200.4 32.00 0.00 32.00 — Monosulfide heavies (no thiol) 2 0 1 1 298.5  0.00 10.74  10.74 0 Monothiol monosulfide heavies 2 1 1 2 332.6  9.64 9.64 19.28 1 Dithiol monosulfide heavies 2 2 1 3 366.6 17.49 8.74 26.23 2 N is the total number of substituted tricyclodecanyl and tricyclodecenyl moieties, —SH is the number of thiol groups, —S— is the number of sulfide groups, Total S is the total number of sulfur atoms, MW is the molecular weight of the sulfur-containing compound (g/mol), % SH is the wt. % thiol sulfur, % Sulfide is the wt. % sulfide sulfur, % Total S is the wt. % sulfur, and Ratio SH/S is the ratio of wt. % thiol sulfur to wt. % sulfide sulfur.

TABLE II Calculated product characteristics for illustrative polythiol compositions derived from dicyclopentadiene. Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Monothiotricyclodecene 10 1 10 1 10 0.5 0.5 Dithiotricyclodecane 85 85 65 65 50 59.5 59.5 Monosulfide heavies (no thiol) 2 5 8 10 20 30 5 Monothiol monosulfide heavies 2 5 8 10 10 5 5 Dithiol monosulfide heavies 1 4 9 14 10 5 30 % SH 29.5 28.6 25.1 24.4 20.6 20.5 24.9 % Sulfide 0.5 1.4 2.4 3.3 4.0 4.1 3.6 % Total S 30.0 29.9 27.5 27.7 24.6 24.6 28.5 The amount of the respective sulfur-containing compounds is shown in wt. %, % SH is the wt. % thiol sulfur of the composition, % Sulfide is the wt. % sulfide sulfur of the composition, and % Total S is the wt. % sulfur of the composition.

TABLE III Polythiol compositions of Examples 1-10. Example 1 2 3 4 5 6 7 8 9 10 Reactor Size 1.5 L 1.5 L 5 L 5 L 5 L 5 L 5 L 5 L 5 L 5 L Wt. DCPD 100 g 100 g 250 g 250 g 250 g 250 g 250 g 250 g 250 g 250 g Wt. H₂S 800 g 800 g 2800 g 2800 g 2800 g 2800 g 2800 g 2800 g 2800 g 2800 g Wt. Acetone 100 g 100 g 200 g 200 g 200 g 200 g 200 g 200 g 200 g 200 g Wt. % TEP 1.00 3.00 2.40 2.40 2.40 2.40 2.40 2.40 2.40 2.40 Wt. % Irgacure 500 0.50 3.00 1.20 1.20 1.20 1.20 1.20 1.20 1.20 1.20 H₂S:olefin ratio 15 15 21 21 21 21 21 21 21 21 Time (min) 100 90 150 120 120 120 120 150 120 130 % Conv. (Raman) — — 77.1 76.8 77.3 76.5 75.8 71.9 80.7 79.7 % SH 23.6 24.8 23.4 24.4 25.3 24.9 24.6 24.2 23.8 24.6 GC Analysis (area %) % dicyclopentadiene 0.18 0.13 0.11 0.31 0.31 0.33 0.31 0.22 0.32 0.31 % TETP 0.78 1.27 0.86 0.93 0.95 0.95 0.91 0.83 0.92 0.96 % monothiotricyclodecenes 44.58 47.37 39.56 34.33 37.31 36.46 36.36 44.36 34.63 37.66 % dithiotricyclodecanes 39.67 41.78 45.25 47.06 46.02 46.82 46.86 42.15 48.19 48.08 % heavies 12.57 7.31 12.38 14.59 13.45 13.91 13.70 10.66 13.39 11.05 GC Analysis represents area under the curve (area %), which is comparable to wt. %, DCPD = dicyclopentadiene, TEP = triethylphosphite, % SH = wt. % thiol sulfur of the composition, % TETP = amount of triethylthiophospate, % monothiotricyclodecenes = amount of monothiotricyclodecene compounds, % dithiotricyclodecanes = amount of dithiotricyclodecane compounds, and % heavies = amount of intermolecular sulfide compounds.

TABLE IV Ore composition summary (wt. %). Ore Cu Fe Mo S Insolubles Ore 2 0.48 2.70 0.010 0.97 90.5 Ore 3 0.34 2.28 0.024 1.03 91.5 Ore 1 0.26 2.99 0.039 0.98 82.7 Ore 4 0.42 2.28 0.009 1.59 77.7

TABLE V Summary of the mining chemical collector experiments of Examples 12-19. Recoveries % Grade % Ore Example Cu Mo Fe Cu Mo Dosage Ore 3 12 - Standard 92.8 93.7 38.7 4.8 0.34 13 - Polythiol 93.2 96.7 43.5 6.3 0.48 15 uL Ore 1 14 - Standard 91.2 92.8 24.4 9.7 1.37 15 - Polythiol 88.4 94.1 19.0 7.8 1.21 15 uL Ore 2 16 - Standard 88.8 72.1 33.3 9.3 0.14 17 - Polythiol 55.8 65.8 15.9 6.2 0.17 25 uL Ore 4 18 - Standard 89.9 67.3 48.9 3.5 0.06 19 - Polythiol 75.5 86.4 22.0 6.8 0.10 15 uL

TABLE VI Summary of the mining chemical collector experiments of Examples 15 and 20-25. Recoveries % Grade % Ore Example Cu Mo Fe Cu Mo Dosage Ore 1 15 - Polythiol 88.4 94.1 19.0 7.8 1.21 15 μL  Ore 1 20 - TDDM 91.2 93.7 17.6 11.4  1.84 5 μL Ore 1 21 - TDDM 91.3 93.7 18.5 10.2  1.62 9 μL Ore 1 22 - TDDM 89.9 90.1 13.0 7.8 1.15 3 μL Ore 1 23 - TDDM 90.9 90.7 13.9 7.2 1.02 7 μL Ore 1 24 - TDDM 91.9 93.0 16.0 7.1 1.03 15 μL  Ore 1 25 - NDDM 91.1 92.2 18.9 8.0 0.99 26 μL 

The invention is described above with reference to numerous aspects and embodiments, and specific examples. Many variations will suggest themselves to those skilled in the art in light of the above detailed description. All such obvious variations are within the full intended scope of the appended claims. Other embodiments of the invention can include, but are not limited to, the following (embodiments are described as “comprising” but, alternatively, can “consist essentially of” or “consist of”):

Embodiment 1

A polythiol composition comprising sulfur-containing compounds, the sulfur-containing compounds comprising:

(i) less than 10 wt. % monothiotricyclodecene compounds;

(ii) at least 40 wt. % dithiotricyclodecane compounds; and

(iii) from 5 to 40 wt. % of a heavy fraction comprising intermolecular sulfide compounds having at least one intermolecular sulfide group (—S—), at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optionally at least one thiol sulfur group (—SH).

Embodiment 2

The polythiol composition of embodiment 1, wherein the monothiotricyclodecene compounds comprise a compound having the structure:

Embodiment 3

The polythiol composition of embodiment 1 or 2, wherein the monothiotricyclodecene compounds comprise a compound having the structure:

Embodiment 4

The polythiol composition of any one of the preceding embodiments, wherein the dithiotricyclodecane compounds comprise a compound having the structure:

Embodiment 5

The polythiol composition of any one of the preceding embodiments, wherein the heavy fraction comprises a compound having one of the following structures:

or combinations thereof.

Embodiment 6

The polythiol composition of any one of the preceding embodiments, wherein the heavy fraction comprises a compound having the following structure:

Embodiment 7

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds of the polythiol composition have an amount of the heavy fraction (comprising intermolecular sulfide compounds) in any range disclosed herein, e.g., from 5 wt. % to 35 wt. %, from 10 wt. % to 40 wt. %, from 10 wt. % to 35 wt. %, from 10 wt. % to 30 wt. %, from 15 wt. % to 35 wt. %, or from 15 wt. % to 30 wt. %.

Embodiment 8

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds of the polythiol composition have an amount of the dithiotricyclodecane compounds in any range disclosed herein, e.g., from 40 wt. % to 90 wt. %, from 40 wt. % to 80 wt. %, from 50 wt. % to 90 wt. %, from 50 wt. % to 80 wt. %, from 60 wt. % to 85 wt. %, or from 60 wt. % to 80 wt. %.

Embodiment 9

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds of the polythiol composition have a maximum amount of monothiotricyclodecene compounds in any range disclosed herein, e.g., less than or equal to 8 wt. %, less than or equal to 5 wt. %, less than or equal to 3 wt. %, less than or equal to 2 wt. %, or less than or equal to 1 wt. %.

Embodiment 10

The polythiol composition of any one of the preceding embodiments, wherein the polythiol composition has a maximum amount of sulfur-free olefin-containing compounds in any range disclosed herein, e.g., less than or equal to 2 wt. %, less than or equal to 1 wt. %, less than or equal to 0.5 wt. %, or less than or equal to 0.1 wt. %.

Embodiment 11

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds comprise:

(i) less than 5 wt. % (or less than 2 wt. %) of the monothiotricyclodecene compounds;

(ii) from 40 wt. % to 90 wt. % (or from 60 wt. % to 80 wt. %) of the dithiotricyclodecane compounds; and

(iii) from 10 to 40 wt. % (or from 15 to 35 wt. %) of the heavy fraction comprising intermolecular sulfide compounds

Embodiment 12

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds of the polythiol composition have an average weight percentage of thiol sulfur (—SH) in any range of average weight percentages of thiol sulfur disclosed herein, e.g., from 18 to 30 wt. %, from 19 to 29 wt. %, or from 20 to 28 wt. %.

Embodiment 13

The polythiol composition of any one of the preceding embodiments, wherein the sulfur-containing compounds of the polythiol composition have an average weight percentage of sulfide sulfur (—S—) in any range of average weight percentages of sulfide sulfur disclosed herein, e.g., from 0.5 to 4.3 wt. %, from 1 to 4.2 wt. %, or from 1.2 to 3.8 wt. %.

Embodiment 14

The polythiol composition of any one of the preceding embodiments, wherein the polythiol composition does not have an offensive odor (or the sulfur-containing compounds of the polythiol composition do not have an offensive odor).

Embodiment 15

The polythiol composition of any one of the preceding embodiments, wherein the polythiol composition is produced by a process comprising:

1) contacting:

-   -   a) dicyclopentadiene;     -   b) H₂S; and     -   c) optionally, a phosphite compound; and

2) forming the polythiol composition;

wherein a molar ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene is in a range from 2:1 to 500:1.

Embodiment 16

The composition of embodiment 15, wherein the process further comprises a step of removing at least a portion of the H₂S, of the phosphite compound (if used), of the dicyclopentadiene, of non-sulfide monothiol compounds, or combinations thereof, from the polythiol composition.

Embodiment 17

The composition of embodiment 16, wherein the H₂S, the phosphite compound (if used), the dicyclopentadiene, the non-sulfide monothiol compounds, or combinations thereof, are removed by wiped film evaporation, distillation, short path distillation, or a combination thereof.

Embodiment 18

The composition of any one of embodiments 15-17, wherein the molar ratio of H₂S to carbon-carbon double bonds of the dicyclopentadiene is in any range of molar ratios of H₂S to carbon-carbon double bonds disclosed herein, e.g., from 2:1 to 150:1, from 2:1 to 50:1, from 3:1 to 50:1, from 5:1 to 35:1, or from 8:1 to 25:1.

Embodiment 19

The composition of any one of embodiment 15-18, wherein a molar ratio of the phosphite compound to carbon-carbon double bonds of the dicyclopentadiene is in any range of molar ratios of the phosphite compound to carbon-carbon double bonds disclosed herein, e.g., from 0.0005:1 to 0.10:1, or from 0.005:1 to 0.05:1.

Embodiment 20

The composition of embodiment 19, wherein the phosphite compound comprises a compound having the formula, P(OR¹)₃, wherein each R¹ is independently any C₁-C₁₀ hydrocarbyl group disclosed herein.

Embodiment 21

The composition of embodiment 19, wherein the phosphite compound comprises trimethylphosphite, triethylphosphite, tributylphosphite, or any combination thereof.

Embodiment 22

The composition of any one of embodiments 15-21, wherein the polythiol composition is formed at a temperature in any range of temperatures disclosed herein, e.g., from −30° C. to 150° C., from −20° C. to 130° C., from −10° C. to 100° C., from −5° C. to 80° C., or from 0° C. to 60° C.

Embodiment 23

The composition of any one of embodiments 15-22, wherein the polythiol composition is formed in the presence of electromagnetic radiation.

Embodiment 24

The composition of any one of embodiments 15-22, wherein the polythiol composition is formed in the presence of ultraviolet light.

Embodiment 25

The composition of any one of embodiments 15-22, wherein the polythiol composition is formed in the presence of ultraviolet light and a photoinitiator, and wherein the photoinitiator is present at an amount within any weight percentage range disclosed herein, e.g., less than or equal to 5 wt. %, less than or equal to 3 wt. %, less than or equal to 2 wt. %, or less than or equal to 1.5 wt. %, based on the weight of the dicyclopentadiene.

Embodiment 26

The composition of any one of embodiments 15-22, wherein the polythiol composition is formed in the presence of a free radical initiator, and wherein the free radical initiator is present at an amount within any weight percentage range disclosed herein, e.g., from 0.1 to 9 wt. %, or from 0.1 to 2 wt. %, based on the weight of the dicyclopentadiene.

Embodiment 27

The composition of embodiment 26, wherein the polythiol composition is formed at conditions suitable for a thermal decomposition of the free radical initiator.

Embodiment 28

The composition of any one of embodiments 15-27, wherein the polythiol composition is formed in the presence of any solvent disclosed herein, e.g., a hydrocarbon solvent, an aromatic hydrocarbon solvent, a ketone solvent, an alcohol solvent, an ether solvent, or any combination thereof.

Embodiment 29

The composition of any one of embodiments 15-28, wherein at least 60%, at least 70%, or at least 80%, of the carbon-carbon double bonds of the dicyclopentadiene have reacted to form a sulfur-containing group.

Embodiment 30

A collector composition comprising the polythiol composition of any one of embodiments 1-29.

Embodiment 31

A collector composition comprising water and the polythiol composition of any one of embodiments 1-29.

Embodiment 32

A collector composition comprising the polythiol composition of any one of embodiments 1-29 and any suitable pH control agent or any pH control agent disclosed herein, e.g., a carbonate compound, or lime.

Embodiment 33

A collector composition comprising the polythiol composition of any one of embodiments 1-29 and any suitable frothing agent or any frothing agent disclosed herein, e.g., MIBC (methyl isobutyl carbinol), pine oil, NALFLOTE® 9837, Cytec OREPREP® X-133, etc., or any combination thereof.

Embodiment 34

A collector composition comprising the polythiol composition of any one of embodiments 1-29, a frothing agent, a pH control agent, and water.

Embodiment 35

The collector composition of any one of embodiments 30-34, wherein the collector composition further comprises any (second) suitable collector agent or any second collector agent disclosed herein, e.g., a xanthate, a xanthic ester, a thionocarbonate, a dialkyl dithiophosphate, etc., or any combination thereof.

Embodiment 36

A flotation process for the recovery of a metal from an ore, the process comprising contacting the ore with the collector composition of any one of embodiments 31-35 or the polythiol composition of any one of embodiments 1-29.

Embodiment 37

The process of embodiment 36, wherein the metal comprises a transition metal.

Embodiment 38

The process of embodiment 36, wherein the metal comprises gold, silver, platinum, copper, nickel, iron, lead, zinc, molybdenum, cobalt, chromium, or combinations thereof.

Embodiment 39

The process of embodiment 36, wherein the metal comprises copper.

Embodiment 40

The process of embodiment 36, wherein the metal comprises molybdenum.

Embodiment 41

The process of any one of embodiments 36-40, wherein the ore comprises a copper-bearing ore and/or a molybdenum-bearing ore.

Embodiment 42

The process of any one of embodiments 36-40, wherein the ore comprises chalcopyrite.

Embodiment 43

The process of any one of embodiments 36-40, wherein the ore comprises chalcocite.

Embodiment 44

The process of any one of embodiments 36-43, wherein the collector composition (excluding the weight of water) and the ore are contacted at a weight ratio in a range from about 0.001 lb of collector composition per ton of ore to about 10 lb of collector composition per ton of ore.

Embodiment 45

The process of any one of embodiments 36-44, wherein the % recovery of copper and/or molybdenum is at least about 80 wt. %, at least about 85 wt. %, or at least about 90 wt. %.

Embodiment 46

The process of any one of embodiments 36-45, wherein the % recovery of copper and/or molybdenum is greater than a mine standard, or within about 5 wt. %, or within about 2 wt. %, of a mine standard, under the same flotation conditions.

Embodiment 47

The process of any one of embodiments 36-46, wherein the % recovery of copper and/or molybdenum is greater than that of TDDM or NDDM, or within about 5 wt. %, or within about 2 wt. %, of the % recovery using TDDM or NDDM, under the same flotation conditions. 

We claim:
 1. A collector composition comprising water and a polythiol composition comprising sulfur-containing compounds, the sulfur-containing compounds comprising: (i) less than 10 wt. % monothiotricyclodecene compounds; (ii) at least 40 wt. % dithiotricyclodecane compounds; and (iii) from 5 wt. % to 40 wt. % of a heavy fraction comprising intermolecular sulfide compounds having at least one intermolecular sulfide group (—S—), at least two groups independently selected from a tricyclodecenyl group and a tricyclodecanyl group, and optionally at least one thiol sulfur group (—SH).
 2. The collector composition of claim 1, wherein the sulfur-containing compounds comprise: (i) less than 2 wt. % of monothiotricyclodecene compounds; (ii) from 60 wt. % to 80 wt. % of dithiotricyclodecane compounds; and (iii) from 15 wt. % to 35 wt. % of the heavy fraction.
 3. The collector composition of claim 1, wherein the collector composition further comprises a pH control agent.
 4. The collector composition of claim 1, wherein the collector composition further comprises a frothing agent.
 5. The collector composition of claim 1, wherein the collector composition comprises water, the polythiol composition, a frothing agent, and a pH control agent.
 6. The collector composition of claim 1, wherein the collector composition further comprises a second mining chemical collector agent.
 7. The collector composition of claim 1, wherein the monothiotricyclodecene compounds comprise a compound having the structure:


8. The collector composition of claim 1, wherein the dithiotricyclodecane compounds comprise a compound having the structure:


9. The collector composition of claim 1, wherein the heavy fraction comprises at least one of the following compounds:

or combinations thereof.
 10. The collector composition of claim 1, wherein the polythiol composition contains less than or equal to 1 wt. % of sulfur-free olefin-containing compounds.
 11. The collector composition of claim 10, wherein the polythiol composition contains less than or equal to 0.1 wt. % of sulfur-free olefin-containing compounds.
 12. The collector composition of claim 1, wherein the sulfur-containing compounds are characterized by: an average of from 0.5 wt. % to 4.3 wt. % sulfide sulfur; and an average of from 18 wt. % to 30 wt. % thiol sulfur.
 13. The collector composition of claim 12, wherein the sulfur-containing compounds are characterized by: an average of from 1 wt. % to 4.2 wt. % sulfide sulfur; and an average of from 20 wt. % to 28 wt. % thiol sulfur.
 14. The collector composition of claim 3, wherein the pH control agent comprises a carbonate compound, lime, or both.
 15. The collector composition of claim 4, wherein the frothing agent comprises pine oil, methyl isobutyl carbinol (MIBC), NALFLOTE® 9837, Cytec OREPREP® X-133, or any combination thereof.
 16. The collector composition of claim 5, wherein the sulfur-containing compounds comprise: (i) less than 5 wt. % of monothiotricyclodecene compounds; (ii) from 40 wt. % to 90 wt. % of dithiotricyclodecane compounds; and (iii) from 10 wt. % to 40 wt. % of the heavy fraction.
 17. The collector composition of claim 16, wherein: the amount of water in the collector composition is greater than 75 wt. %; and the amount of the polythiol composition in the collector composition, excluding the weight of water in the collector composition, is less than 0.1 wt. %.
 18. The collector composition of claim 5, wherein the sulfur-containing compounds comprise: (i) less than 2 wt. % of monothiotricyclodecene compounds; (ii) from 60 wt. % to 80 wt. % of dithiotricyclodecane compounds; and (iii) from 15 wt. % to 35 wt. % of the heavy fraction.
 19. The collector composition of claim 18, wherein: the amount of water in the collector composition is greater than 95 wt. %; and the amount of the polythiol composition in the collector composition, excluding the weight of water in the collector composition, is less than 0.01 wt. %.
 20. The collector composition of claim 6, wherein the second mining chemical collector agent comprises a xanthate, a xanthic ester, a thionocarbonate, a dialkyl dithiophosphate, or any combination thereof. 